Instructions
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Open the Zimbra Admin web client. This is usually held in port 7071 of the normal mail URL.
mail.example.com:7071/zimbraAdmin/
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On the left hand side, select Manage → Accounts.
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In the top right corner, select the Gear icon and select New.
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A New Account window will appear. Enter all the desired information and a password for the new account here and select Finish when you are done.